The following national train companies operate in the UK:

Arriva Trains Wales

http://www.arrivatrainswales.co.uk

Chiltern Railways

Operates trains between London, Birmingham, High Wycombe and Aylesbury.

http://www.chilternrailways.co.uk

CrossCountry (XC)

http://www.crosscountrytrains.co.uk

London Docklands Light Railway

Operates trains from the Tower of London to Canary Wharf and Isle of Dogs.

https://tfl.gov.uk/modes/dlr

East Coast Railway

Operates trains from London (Kings Cross) to the North east of England and Scotland. Travelling between London, Leeds, York, Newcastle, Edinburgh etc.

http://www.eastcoast.co.uk

East Midlands Trains

Operates trains to London and stations throughout the East Midlands, including Leicester, Derby, Sheffield, Nottingham and Lincoln.

http://www.eastmidlandstrains.co.uk

Eurostar

Operates trains from London Waterloo to: Antwerpen, Bruges, Ghent, Brussels, Namur, Lille, Paris, Disneyland Paris and Ski Trains.

http://www.eurostar.com

Great Western

Operates trains between London Paddington, South Wales, The Cotswolds and the West of England.

https://www.gwr.com

First TransPennine Express

Operates trains in the North of England, from Leeds to Liverpool, Manchester to Middlesbrough etc.

http://www.tpexpress.co.uk

Gatwick Express

Operates trains between Gatwick Airport and London Victoria Railway Stations.

http://www.gatwickexpress.com

Heathrow Express

Operates trains from Heathrow to London Paddington, every 15 minutes.

http://www.heathrowexpress.co.uk

Hull Trains

Direct London to Hull service.

http://www.hulltrains.co.uk

London Midland

Operates train services through the midlands from London to Birmingham and Liverpool.

http://www.londonmidland.com

London Underground

London's underground railway - The Tube.

http://www.tfl.gov.uk

National Express East Anglia

Operates train services in East Anglia.

http://www.nationalexpresseastanglia.com

Northern Rail

Operates local and inter-regional train services in the North and North East of England.

http://www.northernrail.org

ScotRail

Operating local and long distance services around Scotland. Also operates the Caledonian Sleeper services between London and Scotland.

https://www.scotrail.co.uk

South West Trains

Operates trains from London Waterloo to the South West.

http://www.southwesttrains.co.uk

Southern Railway

Operates train services in south London, between central London and the South coast, through East and West Sussex, Surrey and also parts of Kent and Hampshire.

http://www.southernrailway.com

Stanstead Express

Operates train shuttle service to Stanstead Airport.

http://www.stanstedexpress.com

Virgin Trains

Operates train services for destinations up and down the country, from London Euston to Glasgow and Edinburgh.

http://www.virgintrains.co.uk

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